(Z)-Selective cross-dimerization of arylacetylenes with silylacetylenes catalyzed by vinylideneruthenium complexes.

نویسندگان

  • Hiroyuki Katayama
  • Hiroshi Yari
  • Masaki Tanaka
  • Fumiyuki Ozawa
چکیده

The vinylideneruthenium(II) complexes bearing bulky and basic tertiary phosphine ligands, RuCl2(=C=CHPh)L2 (L = PPri3, PCy3), serve as good catalyst precursors for (Z)-selective cross-dimerization between arylacetylenes and silylacetylenes in the presence of N-methylpyrrolidine.

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عنوان ژورنال:
  • Chemical communications

دوره 34  شماره 

صفحات  -

تاریخ انتشار 2005